PA2096 Palladium(II) Nitrate Hydrate Powder (CAS No.207596-32-5)

SECTION 1. IDENTIFICATION

Product Name: Palladium(II) Nitrate Dihydrate

CAS #: 32916-07-7

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Oxidizing solids (Category 1), H271

Corrosive to Metals (Category 1), H290

Acute toxicity, Oral (Category 4), H302

Skin corrosion (Sub-category 1B), H314

Serious eye damage (Category 1), H318

Short-term (acute) aquatic hazard (Category 1), H400

Long-term (chronic) aquatic hazard (Category 1), H410

Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word Danger

Hazard statement(s)

H271 May cause fire or explosion; strong oxidizer.

H290 May be corrosive to metals.

H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P210 Keep away from heat.

P220 Keep/Store away from clothing/ combustible materials.

P221 Take any precaution to avoid mixing with combustibles.

P234 Keep only in original container.

P260 Do not breathe dust or mist.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face

protection.

P283 Wear fire/ flame resistant/ retardant clothing.

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel

unwell. Rinse mouth.

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated

clothing. Rinse skin with water/shower.

P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Immediately call a POISON CENTER/doctor.

P305 + P351 + P338 +

P310

IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue

rinsing. Immediately call a POISON CENTER/doctor.

P306 + P360 IF ON CLOTHING: rinse immediately contaminated clothing and

skin with plenty of water before removing clothes.

P363 Wash contaminated clothing before reuse.

P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant

foam to extinguish.

P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight

fire remotely due to the risk of explosion.

P390 Absorb spillage to prevent material damage.

P391 Collect spillage.

P405 Store locked up.

P406 Store in corrosive resistant container with a resistant inner

liner.

P501 Dispose of contents/ container to an approved waste disposal

plant.

Hazards not otherwise classified (HNOC) or not covered by GHS - none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Formula : N2O6Pd · xH2O

Molecular weight : 230.43 g/mol

CAS-No. : 32916-07-7

Component: Palladium(II) nitrate hydrate

Classification

Ox. Sol. 1; Met. Corr. 1;

Acute Tox. 4; Skin Corr.

1B; Eye Dam. 1; AquaticAcute 1; Aquatic Chronic

1; H271, H290, H302,

H314, H318, H400, H410

M-Factor - Aquatic Acute:

10

Concentration

<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of

dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration.

Consult a physician.

In case of skin contact

Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of

water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a

physician.Continue rinsing eyes during transport to hospital.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse

mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section

2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Dry powder Dry sand

Special hazards arising from the substance or mixture

Nitrogen oxides (NOx)

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

Use water spray to cool unopened containers.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas.

Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up

Sweep up and shovel. Contain spillage, and then collect with an electrically protected

vacuum cleaner or by wet-brushing and place in container for disposal according to local

regulations (see section 13). Keep in suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Further processing

of solid materials may result in the formation of combustible dusts. The potential for

combustible dust formation should be taken into consideration before additional processing

occurs.

Provide appropriate exhaust ventilation at places where dust is formed.Keep away from

sources of ignition - No smoking.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Light sensitive. hygroscopic Keep in a dry place.

Storage class (TRGS 510): 5.1A: Strongly oxidizing hazardous materials

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands

before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN

166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove

removal technique (without touching glove's outer surface) to avoid skin contact

with this product. Dispose of contaminated gloves after use in accordance with

applicable laws and good laboratory practices. Wash and dry hands.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 minMaterial tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 min

Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail

sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which

differ from EN 374, contact the supplier of the CE approved gloves. This

recommendation is advisory only and must be evaluated by an industrial hygienist

and safety officer familiar with the specific situation of anticipated use by our

customers. It should not be construed as offering an approval for any specific use

scenario.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must

be selected according to the concentration and amount of the dangerous substance

at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a fullface

particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as

a backup to engineering controls. If the respirator is the sole means of protection,

use a full-face supplied air respirator. Use respirators and components tested and

approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Discharge into the environment must be avoided.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

a) Appearance Form: powder

Colour: brown

b) Odour No data available

c) Odour Threshold No data available

d) pH No data available

e) Melting

point/freezing point

No data available

f) Initial boiling point

and boiling range

No data available

g) Flash point ()No data available

h) Evaporation rate No data available

i) Flammability (solid,

gas)

No data available

j) Upper/lower

flammability or

explosive limits

No data available

k) Vapour pressure No data availablel) Vapour density No data available

m) Relative density No data available

n) Water solubility No data available

o) Partition coefficient:

n-octanol/water

No data available

p) Auto-ignition

temperature

No data available

q) Decomposition

temperature

No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties May cause fire or explosion; strong oxidizer.

9.2 Other safety information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong reducing agents, Strong acids

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - 200 - 2,000 mg/kg

(OECD Test Guideline 423)

Inhalation: No data available

Dermal: No data available

No data available

Skin corrosion/irritation

Skin - in vitro assay

Result: Corrosive

(OECD Test Guideline 435)

Serious eye damage/eye irritation

No data available

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% is

identified as probable, possible or confirmed human carcinogen by IARC.

NTP: No component of this product present at levels greater than or equal to 0.1% is

identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is

on OSHA’s list of regulated carcinogens.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not

been thoroughly investigated.

Stomach - Irregularities - Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

No data available

Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - 0.063

mg/l - 72 h

(OECD Test Guideline 201)

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not

conducted

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or

disposal.

Very toxic to aquatic life with long lasting effects.

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Burn in a

chemical incinerator equipped with an afterburner and scrubber but exert extra care in

igniting as this material is highly flammable. Contact a licensed professional waste

disposal service to dispose of this material.

Contaminated packagingDispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

UN number: 1477 Class: 5.1 Packing group: II

Proper shipping name: Nitrates, inorganic, n.o.s.

Reportable Quantity (RQ):

Poison Inhalation Hazard: No

IMDG

UN number: 1477 Class: 5.1 Packing group: II EMS-No: F-A, S-Q

Proper shipping name: NITRATES, INORGANIC, N.O.S.

IATA

UN number: 1477 Class: 5.1 Packing group: II

Proper shipping name: Nitrates, inorganic, n.o.s.

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

This material does not contain any components with a section 302 EHS TPQ.

SARA 313 Components

This material does not contain any chemical components with known CAS numbers that

exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section

313.

SARA 311/312 Hazards

Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.